Scandium trifluoromethanesulfonate, ti a npe ni Scandium (III) triflate, jẹ kemikali kemikali pẹlu agbekalẹ Sc (SO3CF3) 3, iyọ ti o ni awọn cations scandium Sc3+ ati triflate SO3CF3? aniyan.
Scandium (III) triflate jẹ ohun ti nṣiṣe lọwọ lalailopinpin, daradara, imularada ati ayase acylation atunlo. O jẹ ayase pataki fun Friedel-Crafts acylation, awọn aati Diels-Alder ati awọn aati idawọle erogba-erogba miiran. O tun stereochemically ṣe itọsi polymerization ti ipilẹṣẹ ti acrylates. Scandium (III) triflate eka ti (4′S,5′S)-2,6-bis[4′-(triisopropylsilyl)oxymethyl-5′-phenyl-1′,3′-oxazolin-2′-yl]pyridine ti gba iṣẹ bi ayase fun ifaseyin Friedel-Crafts asymmetric laarin awọn indoles ti o rọpo ati methyl (E) -2-oxo-4-aryl-3-butenoates.
| Awọn nkan | Sipesifikesonu | Awọn abajade idanwo |
| Ifarahan | Funfun tabi Paa-funfun ri to | Ni ibamu |
| Mimo | 98% iṣẹju | 99.3% |
| Ipari: Oye. | ||
Scandium (III) trifluoromethanesulfonate ti wa ni lilo pupọ bi ayase ni hydrothiolation, yiyan meji-electron idinku ti atẹgun nipasẹ ferrocene awọn itọsẹ ati vinylogous Fridel-crafts alkylation ti indoles ati pyrrole ninu omi. O ṣe alabapin ninu afikun Mukaiyama aldol ati stereochemically ṣe itọsi polymerization radical ti acrylates. O ṣe bi ayase acid Lewis ati lilo ninu iṣelọpọ ti bullvalone nipasẹ sulfur ylide ti o ni iduroṣinṣin.
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